Weber's law is probably purely physiological.
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James, William
One can express this state of things otherwise by saying that the whole of the stimulus does not seem to be effective in giving us the perception of 'more,' and the simplest interpretation of such a state of things would be physical. The loss of effect would take place in the nervous system. If our feelings resulted from a condition of the nerve-molecules which it grew ever more difficult for the stimulus to increase, our feelings would naturally grow at a slower rate than the stimulus itself. An ever larger part of the latter's work would go to overcoming the resistances, and an ever smaller part to the realization of the feeling-bringing state. Weber's law would thus be a sort of law of friction in the neural machine.[462] Just how these inner resistances and frictions are to be conceived is a speculative question. Delbœuf has formulated them as fatigue; Bernstein and Ward, as irradiations. The latest, and probably the most 'real,' hypothesis is that of Ebbinghaus, who supposes that the intensity of sensation depends on the number of neural molecules which are disintegrated in the unit of time. There are only a certain number at any time which are capable of disintegrating; and whilst most of these are in an average condition of instability, some are almost stable and some already near to decomposition. The smallest stimuli affect these latter molecules only; and as they are but few, the sensational effect from adding a given quantity of stimulus at first is relatively small.
Medium stimuli affect the majority of the molecules, but affect fewer and fewer in proportion as they have already diminished their number. The latest additions to the stimuli find all the medium molecules already disintegrated, and only affect the small relatively indecomposable remainder, thus giving rise to increments of feeling which are correspondingly small. (Pflüger's Archiv, 45, 113.)
It is surely in some such way as this that Weber's law is to be interpreted, if it ever is. The Fechnerian Maasformel and the conception of it as an ultimate 'psychophysic law' will remain an 'idol of the den,' if ever there was one. Fechner himself indeed was a German Gelehrter of the ideal type, at once simple and shrewd, a mystic and an experimentalist, homely and daring, and as loyal to facts as to his theories. But it would be terrible if even such a dear old man as this could saddle our Science forever with his patient whimsies, and, in a world so full of more nutritious objects of attention, compel all future students to plough through the difficulties, not only of his own works, but of the still drier ones written in his refutation. Those who desire this dreadful literature can find it; it has a 'disciplinary value;' but I will not even enumerate it in a foot-note. The only amusing part of it is that Fechner's critics should always feel bound, after smiting his theories hip and thigh and leaving not a stick of them standing, to wind up by saying that nevertheless to him belongs the imperishable glory, of first formulating them and thereby turning psychology into an exact science,
"'And everybody praised the duke Who this great fight did win.' 'But what good came of it at last?' Quoth little Peterkin. 'Why, that I cannot tell,' said he, 'But 'twas a famous victory!'"